1) Well, the owner's manual stipulates every 20,000 Km / 12,000 miles for "Check valve clearance."
2) Here's page 282 of the PDF shop manual I bought, which, after a quick look, seems to be the only relevant page:
View attachment 3739
Whether or not that helps you out with this, if you'll be doing your own maintenance you probably ought to get a manual. See this thread I started last year:
If anyone's interested, I received a thumb drive with the C 400 GT shop manual a couple of days ago. This is the one I bought, via eBay: https://www.ebay.com/itm/133967057090 (If the link becomes obsolete at some point, the heading is "BMW C 400 GT K08 WORKSHOP C400GT SERVICE MANUAL ON USB,"...
www.bmw-scooters.com
That's all I got.
(I haven't done this, with only 5,000 miles on my '22 C 400 GT. Plus, I've decided that I'm too old for this sort of thing, so will be letting the dealer mess with this, when the time comes.)